Supramolecular Alloys from Fluorinated Hybrid Tri⁴ Di⁶ Imine Cages.

ABSTRACT: To create innovative materials, efficient control and engineering of pore sizes and their characteristics, crystallinity and stability is required. Eight hybrid Tri⁴ Di⁶ imine cages with a tunable degree of fluorination and one fully fluorinated Tri⁴ Di⁶ imine cage are investigated. Although the fluorinated and the non-fluorinated building blocks used herein differ vastly in reactivity, it was possible to gain control over the outcome of the self-assembly process, by carefully controlling the feed ratio. This represents the first hybrid material based on fluorinated/hydrogenated porous organic cages (POCs). These cages with unlimited miscibility in the solid state were obtained as highly crystalline samples after recrystallization and even showed

SUBMITTER: Kunde T 

PROVIDER: S-EPMC8252657 | biostudies-literature | 2021 Jun

REPOSITORIES: biostudies-literature