Detection and characterization of folded-chain clusters in the structured melt of isotactic polypropyl-ene.

ABSTRACT: Despite ceaseless efforts in past decades, the memory effect of semi-crystalline polymers has not been elucidated completely yet. An important reason why is that residual lamellar crystals in the structured melt are difficult to characterize. Recently, we developed a new small-angle X-ray scattering (SAXS) theory [Li et al. (2019). IUCrJ, 6, 968-983] and Fourier transform method [Li et al. (2020). CrystEngComm, 22, 3042-3058] for lamellar crystals that could derive structural information from SAXS readily. In this study, we tried to employ the new theory and method to characterize residual lamellar crystals in the structured melt. It was found that although scattering peaks cannot be observed in raw scattering profiles, they actually exist. Subtrac

SUBMITTER: Li X 

PROVIDER: S-EPMC8256699 | biostudies-literature | 2021 Jul

REPOSITORIES: biostudies-literature