Synthesis and Thin Films of Thermally Robust Quartet (S = 3/2) Ground State Triradical.

ABSTRACT: High-spin (S = 3/2) organic triradicals may offer enhanced properties with respect to several emerging technologies, but those synthesized to date typically exhibit small doublet quartet energy gaps and/or possess limited thermal stability and processability. We report a quartet ground state triradical 3, synthesized by a Pd(0)-catalyzed radical-radical cross-coupling reaction, which possesses two doublet-quartet energy gaps, ΔE_DQ ≈ 0.2-0.3 kcal mol^-1 and ΔE_DQ2 ≈ 1.2-1.8 kcal mol^-1. The triradical has a 70+% population of the quartet ground state at room temperature and good thermal stability with onset of decomposition at >160 °C under an inert atmosphere. Magnetic properties of 3 are characterized by SQUID mag

SUBMITTER: Shu C 

PROVIDER: S-EPMC8256820 | biostudies-literature | 2021 Apr

REPOSITORIES: biostudies-literature