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Synthesis, Optical Characterizations and Solar Energy Applications of New Schiff Base Materials.


ABSTRACT: A new set of laterally OCH3-substituted photoactive liquid crystalline analogues, 4-hexyloxy phenyl- imino-4'-(3-methoxyphenyl)-4''-alkoxybenzoates, were synthesized and investigated for their mesomorphic behavior. The prepared set constitutes five analogues that differ from each other by the terminally attached compact polar group. Characterization of the synthesized derivatives is conducted using differential scanning calorimetry (DSC), polarized optical microscopy (POM), and UV-spectroscopy. Molecular structures were elucidated by elemental analyses, FT-IR and NMR spectroscopy. DSC and POM investigations indicated that all the prepared derivatives are monomorphic possessing the nematic (N) phase, except for the unsubstituted derivative that is nonmesomorphic. On the other side, the phot

SUBMITTER: Gomha SM 

PROVIDER: S-EPMC8269905 | biostudies-literature | 2021 Jul

REPOSITORIES: biostudies-literature