Dataset Information

Solid-Phase "Self-Hydrolysis" of [Zn(NH₃)₄MoO₄@2H₂O] Involving Enclathrated Water-An Easy Route to a Layered Basic Ammonium Zinc Molybdate Coordination Polymer.

ABSTRACT: An aerial humidity-induced solid-phase hydrolytic transformation of the [Zn(NH₃)₄]MoO₄@2H₂O (compound 1@2H₂O) with the formation of [(NH₄)_xH_(1-x)Zn(OH)(MoO₄)]_n (x = 0.92-0.94) coordination polymer (formally NH₄Zn(OH)MoO₄, compound 2) is described. Based on the isostructural relationship, the powder XRD indicates that the crystal lattice of compound 1@2H₂O contains a hydrogen-bonded network of tetraamminezinc (2+) and molybdate (2-) ions, and there are cavities (O₄N₄(μ-H₁₂) cube) occupied by the two water molecules, which stabilize the crystal structure. Several observa

SUBMITTER: Beres KA

PROVIDER: S-EPMC8272139 | biostudies-literature | 2021 Jun

REPOSITORIES: biostudies-literature

ACCESS DATA

Dataset Information

Solid-Phase "Self-Hydrolysis" of [Zn(NH₃)₄MoO₄@2H₂O] Involving Enclathrated Water-An Easy Route to a Layered Basic Ammonium Zinc Molybdate Coordination Polymer.

OmicsDI is part of the ELIXIR infrastructure

Tweets

Dataset Information

Solid-Phase "Self-Hydrolysis" of [Zn(NH3)4MoO4@2H2O] Involving Enclathrated Water-An Easy Route to a Layered Basic Ammonium Zinc Molybdate Coordination Polymer.

OmicsDI is part of the ELIXIR infrastructure

Tweets

Solid-Phase "Self-Hydrolysis" of [Zn(NH₃)₄MoO₄@2H₂O] Involving Enclathrated Water-An Easy Route to a Layered Basic Ammonium Zinc Molybdate Coordination Polymer.