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Cucurbitimines - imine cages with concave walls.

ABSTRACT: The variety of shape-persistent organic cages by imine bond formation has tremendously enlarged in recent years by using different building blocks (aldehydes and amines) in the condensation reactions. Here, we describe the use of a kinked tetraldehyde to generate pumpkin-shaped cages with concave walls, similar to cucurbiturils.

SUBMITTER: Bourguignon C

PROVIDER: S-EPMC8276630 | biostudies-literature | 2021 Jul

REPOSITORIES: biostudies-literature

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Cucurbitimines - imine cages with concave walls.

Bourguignon Christine C Schindler Dorothee D Zhou Gangxiang G Rominger Frank F Mastalerz Michael M

Organic chemistry frontiers : an international journal of organic chemistry 20210517 14

The variety of shape-persistent organic cages by imine bond formation has tremendously enlarged in recent years by using different building blocks (aldehydes and amines) in the condensation reactions. Here, we describe the use of a kinked tetraldehyde to generate pumpkin-shaped cages with concave walls, similar to cucurbiturils. ...[more]

PMID: 34354838

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