Ontology highlight
ABSTRACT:
SUBMITTER: Huang C
PROVIDER: S-EPMC8278932 | biostudies-literature | 2021 Jul
REPOSITORIES: biostudies-literature
Chemical science 20210609 27
A palladium-catalyzed C-O bond formation reaction between phenols and allenylic carbonates to give 2,3-allenic aromatic ethers with decent to excellent yields under mild reaction conditions has been described. A variety of synthetically useful functional groups are tolerated and the synthetic utility of this method has been demonstrated through a series of transformations of the allene moiety. By applying this reaction as the key step, the total syntheses of naturally occurring allenic aromatic ...[more]