Influence of the Amount of Carbon during the Synthesis of LaFe_0.8Co_0.2O₃/Carbon Hybrid Material in Oxygen Evolution Reaction.

ABSTRACT: The oxygen evolution reaction (OER) and the hydrogen evolution reaction occurred at the anode and cathode, which depends on the electronic structure, morphology, electrochemically active surface area, and charge-transfer resistance of the electrocatalyst. Transition metals like cobalt, nickel, and iron have better OER and oxygen reduction reaction activities. At the same time, transition-metal oxide/carbon hybrid has several applications in electrochemical energy conversion reactions. The rich catalytic site of transition metals and the excellent conductivity of carbon material make these materials as a hopeful electrocatalyst in OER. Carbon-incorporated LaFe_0.8Co_0.2O₃ was prepared by a simple solution combustion method for the development of the best performance of the electrocatalyst. The catalyst can deliver 10 mA/cm² current density at an overpotential of 410 mV with better catalytic stability. The introduction of carbon material improves the dispersion ability of the catalyst and the electrical conductivity. The Tafel slope and onset potential of the best catalyst are 49.1 mV/dec and 1.55 V, respectively.

SUBMITTER: Thomas J 

PROVIDER: S-EPMC8280668 | biostudies-literature | 2021 Jul

REPOSITORIES: biostudies-literature