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Effect of the 2-R-Allyl and Chloride Ligands on the Cathodic Paths of [Mo(η³-2-R-allyl)(α-diimine)(CO)₂Cl] (R = H, CH₃; α-diimine = 6,6'-Dimethyl-2,2'-bipyridine, Bis(p-tolylimino)acenaphthene).

ABSTRACT: The new, formally Mo(II) complexes [Mo(η³-2-R-allyl)(6,6'-dmbipy)(CO)₂Cl] (6,6'-dmbipy = 6,6'-dimethyl-2,2'-bipyridine; 2-R-allyl = allyl for R = H, 2-methallyl for R = CH₃) and [Mo(η³-2-methallyl)(pTol-bian)(CO)₂Cl] (pTol-bian = bis(p-tolylimino)acenaphthene) share, in this rare case, the same structural type. The effect of the anionic π-donor ligand X (Cl^- vs NCS^-) and the 2-R-allyl substituents on the cathodic behavior was explored. Both ligands play a significant role at all stages of the reduction path. While 2e^--reduced [Mo(η³-allyl)(6,6'-dmbipy)(CO)₂]^- is inert when it is ECE-generated from [Mo(η³-allyl)(6,6'-dmbipy)(CO)₂(NCS)], the Cl^-<

SUBMITTER: Taylor JO

PROVIDER: S-EPMC8289335 | biostudies-literature | 2021 Jun

REPOSITORIES: biostudies-literature

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Dataset Information

Effect of the 2-R-Allyl and Chloride Ligands on the Cathodic Paths of [Mo(η³-2-R-allyl)(α-diimine)(CO)₂Cl] (R = H, CH₃; α-diimine = 6,6'-Dimethyl-2,2'-bipyridine, Bis(p-tolylimino)acenaphthene).

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Tweets

Dataset Information

Effect of the 2-R-Allyl and Chloride Ligands on the Cathodic Paths of [Mo(η3-2-R-allyl)(α-diimine)(CO)2Cl] (R = H, CH3; α-diimine = 6,6'-Dimethyl-2,2'-bipyridine, Bis(p-tolylimino)acenaphthene).

OmicsDI is part of the ELIXIR infrastructure

Tweets

Effect of the 2-R-Allyl and Chloride Ligands on the Cathodic Paths of [Mo(η³-2-R-allyl)(α-diimine)(CO)₂Cl] (R = H, CH₃; α-diimine = 6,6'-Dimethyl-2,2'-bipyridine, Bis(p-tolylimino)acenaphthene).