Effective Adsorption of Methyl Orange on Organo-Silica Nanoparticles Functionalized by a Multi-Hydroxyl-Containing Gemini Surfactant: A Joint Experimental and Theoretical Study.

ABSTRACT: A novel multi-hydroxyl-containing gemini surfactant (G₁₆) is first designed for modifying silica precursors (SiNPs), with the purpose of fabricating organic adsorbents targeted at methyl orange (MO). The purity of G₁₆ and structural character of the resultant G₁₆-SiNPs are unveiled through Fourier transform infrared spectroscopy, X-ray diffraction, thermogravimetry-derivative thermogravimetry, scanning electron microscopy, and surface analysis (BET). Compared with SiNPs, G₁₆-SiNPs exhibit enhanced hydrophobicity, enlarged interlayer spacing, and increased thermal weight losses with the modifier availability reaching as high as 100%. Enhanced MO adsorption is obtained from the higher adsorption capacity of G₁₆-SiNPs (401.88 mg/g) than S

SUBMITTER: Wang T 

PROVIDER: S-EPMC8296568 | biostudies-literature | 2021 Jul

REPOSITORIES: biostudies-literature