Redox Activity of Noninnocent 2,2'-Bipyridine in Zinc Complexes: An Experimental and Theoretical Study.

ABSTRACT: We report on a systematical reactivity study of β-diketiminate zinc complexes with redox-active 2,2'-bipyridine (bpy). The reaction of LZnI (L = HC[C(Me)N(2,6-iPr₂C₆H₃)]₂) with NaB(C₆F₅)₄ in the presence of bpy yielded [LZn(bpy)][B(C₆F₅)₄] (1), with bpy serving as a neutral ligand, whereas reduction reactions of LZnI with 1 or 2 equiv of KC₈ in the presence of bpy gave the radical complex LZn(bpy) (2) and [2.2.2-Cryptand-K][LZn(bpy)] (3), in which bpy either acts as a π-radical anion or a diamagnetic dianion, respectively. The paramagnetic nature of 2 was confirmed via solution magnetic susceptibility measurements, and UV-vis spectrosco

SUBMITTER: Li B 

PROVIDER: S-EPMC8296587 | biostudies-literature | 2021 Jul

REPOSITORIES: biostudies-literature