A Tunable Multivariate Metal-Organic Framework as a Platform for Designing Photocatalysts.

ABSTRACT: Catalysts for photochemical reactions underlie many foundations in our lives, from natural light harvesting to modern energy storage and conversion, including processes such as water photolysis by TiO₂. Recently, metal-organic frameworks (MOFs) have attracted large interest within the chemical research community, as their structural variety and tunability yield advantages in designing photocatalysts to address energy and environmental challenges. Here, we report a series of novel multivariate metal-organic frameworks (MTV-MOFs), denoted as MTV-MIL-100. They are constructed by linking aromatic carboxylates and AB₂OX₃ bimetallic clusters, which have ordered atomic arrangements. Synthesized through a solvent-assisted approach, these ordered and multivariate me

SUBMITTER: Wang Y 

PROVIDER: S-EPMC8297731 | biostudies-literature | 2021 May

REPOSITORIES: biostudies-literature