Visualization of gaseous iodine adsorption on single zeolitic imidazolate framework-90 particles.

ABSTRACT: Zeolitic imidazolate frameworks (ZIFs) are very useful as high-capacity iodine (I₂) adsorbents. The adsorption performance is usually probed by measuring a statistical average property over an entire sample consisting of a large number of ZIF particles, leaving the interparticle heterogeneity information among individuals. Here we report a dark-field microscopy (DFM) method to visualize gaseous I₂ adsorption on single ZIF-90 particles in situ and in real time. The adsorption of I₂ is found to alter the scattering spectrum of ZIF-90 particles, inducing a distinct color change from bluewhite to yellow. According to correlating the adsorption amount of gaseous I₂ with the change of B value from DFM images, we quantitatively image the adsorption proc

SUBMITTER: Lei Y 

PROVIDER: S-EPMC8302588 | biostudies-literature | 2021 Jul

REPOSITORIES: biostudies-literature