Synthesis, Characterization, and Non-Covalent Interactions of Palladium(II)-Amino Acid Complexes.

ABSTRACT: The reaction of palladium(II) acetate with acyclic amino acids in acetone/water yields square planar bis-chelated palladium amino acid complexes that exhibit interesting non-covalent interactions. In all cases, complexes were examined by multiple spectroscopic techniques, especially HRMS (high resolution mass spectrometry), IR (infrared spectroscopy), and 1H NMR (nuclear magnetic resonance) spectroscopy. In some cases, suitable crystals for single crystal X-ray diffraction were able to be grown and the molecular structure was obtained. The molecular geometries of the products are discussed. Except for the alanine complex, all complexes incorporate water molecules into the extended lattice and exhibit N-H···O and/or O···(HOH)···O hydrogen bonding interactions. The non-covalent interactions

SUBMITTER: Hobart DB 

PROVIDER: S-EPMC8303679 | biostudies-literature | 2021 Jul

REPOSITORIES: biostudies-literature