Formate-Mediated Cross-Electrophile Reductive Coupling of Aryl Iodides and Bromopyridines.

ABSTRACT: Two catalytic systems for the formate-mediated cross-electrophile reductive coupling of 4-iodoansiole with 6-bromopyridines are described. Using homogenous rhodium or heterogeneous palladium catalysts, the product of reductive biaryl cross-coupling could be formed in moderate yield with excellent levels of chemoselectivity.

SUBMITTER: Schwartz LA 

PROVIDER: S-EPMC8323530 | biostudies-literature | 2021 May

REPOSITORIES: biostudies-literature