Dataset Information

Mixed alkali-ion transport and storage in atomic-disordered honeycomb layered NaKNi₂TeO₆.

ABSTRACT: Honeycomb layered oxides constitute an emerging class of materials that show interesting physicochemical and electrochemical properties. However, the development of these materials is still limited. Here, we report the combined use of alkali atoms (Na and K) to produce a mixed-alkali honeycomb layered oxide material, namely, NaKNi₂TeO₆. Via transmission electron microscopy measurements, we reveal the local atomic structural disorders characterised by aperiodic stacking and incoherency in the alternating arrangement of Na and K atoms. We also investigate the possibility of mixed electrochemical transport and storage of Na⁺ and K⁺ ions in NaKNi₂TeO₆. In particular, we report an average discharge cell voltage of about 4 V and a specific capacity of around 80 mAh g^-1 at low specific currents (i.e., < 10 mA g^-1) when a NaKNi₂TeO₆-based positive electrode is combined with a room-temperature NaK liquid alloy negative electrode using an ionic liquid-based electrolyte solution. These results represent a step towards the use of tailored cathode active materials for "dendrite-free" electrochemical energy storage systems exploiting room-temperature liquid alkali metal alloy materials.

SUBMITTER: Masese T

PROVIDER: S-EPMC8329229 | biostudies-literature | 2021 Aug

REPOSITORIES: biostudies-literature

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Mixed alkali-ion transport and storage in atomic-disordered honeycomb layered NaKNi2TeO6.

Masese Titus T Miyazaki Yoshinobu Y Rizell Josef J Kanyolo Godwill Mbiti GM Chen Chih-Yao CY Ubukata Hiroki H Kubota Keigo K Sau Kartik K Ikeshoji Tamio T Huang Zhen-Dong ZD Yoshii Kazuki K Takahashi Teruo T Ito Miyu M Senoh Hiroshi H Hwang Jinkwang J Alshehabi Abbas A Matsumoto Kazuhiko K Matsunaga Toshiyuki T Fujii Kotaro K Yashima Masatomo M Shikano Masahiro M Tassel Cédric C Kageyama Hiroshi H Uchimoto Yoshiharu Y Hagiwara Rika R Saito Tomohiro T

Nature communications 20210802 1

Honeycomb layered oxides constitute an emerging class of materials that show interesting physicochemical and electrochemical properties. However, the development of these materials is still limited. Here, we report the combined use of alkali atoms (Na and K) to produce a mixed-alkali honeycomb layered oxide material, namely, NaKNi2TeO6. Via transmission electron microscopy measurements, we reveal the local atomic structural disorders characterised by aperiodic stacking and ...[more]

PMID: 34341351

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Project description:In the quest for developing novel and efficient batteries, a great interest has been raised for sustainable K-based honeycomb layer oxide materials, both for their application in energy devices as well as for their fundamental material properties. A key issue in the realization of efficient batteries based on such compounds, is to understand the K-ion diffusion mechanism. However, investigation of potassium-ion (K[Formula: see text]) dynamics in materials using e.g. NMR and related techniques has so far been very challenging, due to its inherently weak nuclear magnetic moment, in contrast to other alkali ions such as lithium and sodium. Spin-polarised muons, having a high gyromagnetic ratio, make the muon spin rotation and relaxation ([Formula: see text]SR) technique ideal for probing ions dynamics in these types of energy materials. Here we present a study of the low-temperature magnetic properties as well as K[Formula: see text] dynamics in honeycomb layered oxide material [Formula: see text] using mainly the [Formula: see text]SR technique. Our low-temperature [Formula: see text]SR results together with complementary magnetic susceptibility measurements find an antiferromagnetic transition at [Formula: see text] K. Further [Formula: see text]SR studies performed at higher temperatures reveal that potassium ions (K[Formula: see text]) become mobile above 200 K and the activation energy for the diffusion process is obtained as [Formula: see text] meV. This is the first time that K[Formula: see text] dynamics in potassium-based battery materials has been measured using [Formula: see text]SR. Assisted by high-resolution neutron diffraction, the temperature dependence of the K-ion self diffusion constant is also extracted. Finally our results also reveal that K-ion diffusion occurs predominantly at the surface of the powder particles. This opens future possibilities for potentially improving ion diffusion as well as K-ion battery device performance using nano-structuring and surface coatings of the particles.

Project description:We introduce a novel chemical preintercalation based synthesis technique based on hydrogen peroxide induced sol-gel process to obtain alkali ion containing ternary layered titanates (MTO, where M = Li, Na, K). Synthesis parameters leading to the formation of single-phase materials with homogeneous elemental distribution are reported for each of the preintercalated ion. Our analyses indicate that the interlayer spacing in the structure of the layered titanates increases with the increase of the radius of the hydrated preintercalated ion. Scanning and transmission electron microscopy imaging revealed morphological diversity: the LTO phase crystallized as nanoplates assembled in "peony-like" spherical agglomerates while NTO and KTO particles exhibited one-dimensional nanobelt or wire-like morphology, with the KTO nanobelts being shorter and more aggregated than the NTO nanobelts. Structural refinement corroborated by electron diffraction and high-resolution transmission electron microscopy revealed that the structure of the LTO phase is built by stacking Ti-O layers containing a single straight layer of connected TiO6 octahedra. The layers in NTO and KTO structures form differently and consist of double Ti-O layers with ragged arrangement of units built by TiO6 octahedra with two titanium rows. The NTO electrodes exhibited the highest electrochemical performance in cells with aqueous 1 M Na2SO4 electrolyte, followed by the KTO electrodes and then LTO electrodes, and this trend is maintained at various scan rates. The established relationships between the structure and electrochemical performance reveal that, in addition to interlayer distance and chemistry of the interlayer region, the structure of the layers can play an important role in charge storage properties of layered oxide electrodes. The double Ti-O layers in the structure of NTO and KTO phases provide a larger number of redox centers which could contribute to the superior electrochemical performance as compared to the LTO electrodes. Our findings indicate that layered materials containing double transition metal oxide layers are promising candidates for exfoliation and assembly with electronically conductive layers with the aim to create 2D heterostructures with high electrochemical performance.

Dataset Information

Mixed alkali-ion transport and storage in atomic-disordered honeycomb layered NaKNi₂TeO₆.

Publications

Mixed alkali-ion transport and storage in atomic-disordered honeycomb layered NaKNi<sub>2</sub>TeO<sub>6</sub>.

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