Role of Host-Guest Interaction in Understanding Polymerisation in Metal-Organic Frameworks.

ABSTRACT: Metal-organic frameworks, MOFs, offer an effective template for polymerisation of polymers with precisely controlled structures within the sub-nanometre scales. However, synthetic difficulties such as monomer infiltration, detailed understanding of polymerisation mechanisms within the MOF nanochannels and the mechanism for removing the MOF template post polymerisation have prevented wide scale implementation of polymerisation in MOFs. This is partly due to the significant lack in understanding of the energetic and atomic-scale intermolecular interactions between the monomers and the MOFs. Consequently in this study, we explore the interaction of varied concentration of styrene, and 3,4-ethylenedioxythiophene (EDOT), at the surface and in the nanochannel of Zn₂(1,4-ndc)₂

SUBMITTER: Wonanke ADD 

PROVIDER: S-EPMC8333864 | biostudies-literature | 2021

REPOSITORIES: biostudies-literature