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Synthesis and crystallographic studies of 2-(di-phenyl-phosphino-thio-yl)-2-(3-oxobut-1-en-yl)ferrocene.

ABSTRACT: As a follow-up to our research on the chemistry of disubstituted ferrocene derivatives, the synthesis and the structure of the title compound, 2-(di-phenyl-phosphino-thio-yl)-2-(3-oxobut-1-en-yl)ferrocene, [Fe(C5H5)(C21H18OPS)], are described. The mol-ecule is built up from a ferrocene unit disubstituted by an S-protected di-phenyl-phosphine group and by a methyl-vinyl-ketone chain. The crystal structure features weak C-H⋯O and C-H⋯S inter-actions, which build a two-dimensional network. This structure is compared to that of the related disubstituted di-phenyl-phosphino ferrocene.

SUBMITTER: Bandyopadhyay U 

PROVIDER: S-EPMC8340968 | biostudies-literature | 2021 Aug

REPOSITORIES: biostudies-literature

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Synthesis and crystallographic studies of 2-(di-phenyl-phosphino-thio-yl)-2-(3-oxobut-1-en-yl)ferrocene.

Bandyopadhyay Uchchhal U   Sundararaju Basker B   Poli Rinaldo R   Manoury Eric E   Daran Jean-Claude JC  

Acta crystallographica. Section E, Crystallographic communications 20210730 Pt 8

As a follow-up to our research on the chemistry of disubstituted ferrocene derivatives, the synthesis and the structure of the title compound, 2-(di-phenyl-phosphino-thio-yl)-2-(3-oxobut-1-en-yl)ferrocene, [Fe(C<sub>5</sub>H<sub>5</sub>)(C<sub>21</sub>H<sub>18</sub>OPS)], are described. The mol-ecule is built up from a ferrocene unit disubstituted by an S-protected di-phenyl-phosphine group and by a methyl-vinyl-ketone chain. The crystal structure features weak C-H⋯O and C-H⋯S inter-actions, whi  ...[more]

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