Self-Assembly of 1D Double-Chain and 3D Diamondoid Networks of Lanthanide Coordination Polymers through In Situ-Generated Ligands: High-Pressure CO₂ Adsorption and Photoluminescence Properties.

ABSTRACT: Two new lanthanide-based coordination polymers, [Sm₂(bzz)(ben)₆(H₂O)₃]·0.5H₂O (1) and [Eu(bbz)(ben)₃] (2), were synthesized and characterized. The described products were formed from in situ-generated benzoate (ben) and N'-benzoylbenzohydrazide (bbz) ligands, which were the products of transformation of originally added benzhydrazide (bzz) under hydrothermal conditions. Compound 1 exhibits a one-dimensional (1D) double-chain structure built up from the connection of the central Sm³⁺ ions with a mixture of bzz and ben ligands. On the other hand, 2 features a 3D network with a 4-connected (6⁶) dia topology constructed from dinuclear [Eu₂(ben)₆] seco

SUBMITTER: Theppitak C 

PROVIDER: S-EPMC8347576 | biostudies-literature | 2021 Jul

REPOSITORIES: biostudies-literature