Zn-N_x sites on N-doped carbon for aerobic oxidative cleavage and esterification of C(CO)-C bonds.

ABSTRACT: Selective cleavage of C-C bonds is very important in organic chemistry, but remains challenging because of their inert chemical nature. Herein, we report that Zn/NC-X catalysts, in which Zn²⁺ coordinate with N species on microporous N-doped carbon (NC) and X denotes the pyrolysis temperature, can effectively catalyze aerobic oxidative cleavage of C(CO)-C bonds and quantitatively convert acetophenone to methyl benzoate with a yield of 99% at 100 °C. The Zn/NC-950 can be applied for a wide scope of acetophenone derivatives as well as more challenging alkyl ketones. Detail mechanistic investigations reveal that the catalytic performance of Zn/NC-950 can be attributed to the coordination between Zn²⁺ and N species to change the electronic state of the metal, synergetic ef

SUBMITTER: Xie C 

PROVIDER: S-EPMC8355145 | biostudies-literature | 2021 Aug

REPOSITORIES: biostudies-literature