Ontology highlight
ABSTRACT:
SUBMITTER: Moussa ME
PROVIDER: S-EPMC8361777 | biostudies-literature | 2021 Jul
REPOSITORIES: biostudies-literature
Moussa Mehdi Elsayed ME Fleischmann Martin M Balázs Gábor G Virovets Alexander V AV Peresypkina Eugenia E Shelyganov Pavel A PA Seidl Michael M Reichl Stephan S Scheer Manfred M
Chemistry (Weinheim an der Bergstrasse, Germany) 20210601 38
The reactions of the cyclo-As<sub>5</sub> complex [Cp*Fe(η<sup>5</sup> -As<sub>5</sub> )] (B) with the Ag<sup>I</sup> and Cu<sup>I</sup> salts of the weakly coordinating anion (WCA) [FAl{OC<sub>6</sub> F<sub>10</sub> (C<sub>6</sub> F<sub>5</sub> )}<sub>3</sub> ]<sup>-</sup> ([FAl]<sup>-</sup> ) are studied. These reactions allow the synthesis of the mononuclear complexes [M(η<sup>5</sup> : η<sup>2</sup> -B)<sub>2</sub> ][FAl] (M=Ag (1), Cu (2)) when a ratio of B/M(FAl) 2 : 1 is used. Compound 1 ...[more]