Electrochemical Generation of Hypervalent Bromine(III) Compounds.

ABSTRACT: In sharp contrast to hypervalent iodine(III) compounds, the isoelectronic bromine(III) counterparts have been little studied to date. This knowledge gap is mainly attributed to the difficult-to-control reactivity of λ³ -bromanes as well as to their challenging preparation from the highly toxic and corrosive BrF₃ precursor. In this context, we present a straightforward and scalable approach to chelation-stabilized λ³ -bromanes by anodic oxidation of parent aryl bromides possessing two coordinating hexafluoro-2-hydroxypropanyl substituents. A series of para-substituted λ³ -bromanes with remarkably high redox potentials spanning a range from 1.86 V to 2.60 V vs. Ag/AgNO₃ was synthesized by the electrochemical method. We demonstrate that t

SUBMITTER: Sokolovs I 

PROVIDER: S-EPMC8362160 | biostudies-literature | 2021 Jul

REPOSITORIES: biostudies-literature