Ontology highlight
ABSTRACT:
SUBMITTER: Sokolovs I
PROVIDER: S-EPMC8362160 | biostudies-literature | 2021 Jul
REPOSITORIES: biostudies-literature
Angewandte Chemie (International ed. in English) 20210609 29
In sharp contrast to hypervalent iodine(III) compounds, the isoelectronic bromine(III) counterparts have been little studied to date. This knowledge gap is mainly attributed to the difficult-to-control reactivity of λ<sup>3</sup> -bromanes as well as to their challenging preparation from the highly toxic and corrosive BrF<sub>3</sub> precursor. In this context, we present a straightforward and scalable approach to chelation-stabilized λ<sup>3</sup> -bromanes by anodic oxidation of parent aryl br ...[more]