Enhancing ion transport in charged block copolymers by stabilizing low symmetry morphology: Electrostatic control of interfaces.

ABSTRACT: Recently, the interest in charged polymers has been rapidly growing due to their uses in energy storage and transfer devices. Yet, polymer electrolyte-based devices are not on the immediate horizon because of the low ionic conductivity. In the present study, we developed a methodology to enhance the ionic conductivity of charged block copolymers comprising ionic liquids through the electrostatic control of the interfacial layers. Unprecedented reentrant phase transitions between lamellar and A15 structures were seen, which cannot be explained by well-established thermodynamic factors. X-ray scattering experiments and molecular dynamics simulations revealed the formation of fascinating, thin ionic shell layers composed of ionic complexes. The ionic liquid cations of these complexes predomin

SUBMITTER: Min J 

PROVIDER: S-EPMC8364204 | biostudies-literature | 2021 Aug

REPOSITORIES: biostudies-literature