Host-Guest Interactions Between Metal-Organic Frameworks and Air-Sensitive Complexes at High Temperature.

ABSTRACT: The host-guest chemistry of metal-organic frameworks (MOFs) has been attracting increasing attention owing to the outstanding properties derived from MOFs-guests combinations. However, there are large difficulties involved in the syntheses of the host-guest MOF systems with air-sensitive metal complexes. In addition, the behaviors on host-guest interactions in the above systems at high temperature are not clear. This study reported the synthetic methods for host-guest systems of metal-organic framework and air-sensitive metal complexes via a developed chemical vapor infiltration process. With the synchrotron X-ray powder diffraction (XRPD) measurements and Fourier Transform infrared spectroscopy (FTIR), the successful loadings of Fe(CO)₅ in HKUST-1 and NH₂-MIL-101(Al)

SUBMITTER: Huang B 

PROVIDER: S-EPMC8369409 | biostudies-literature | 2021

REPOSITORIES: biostudies-literature