Revealing the chirality origin and homochirality crystallization of Ag₁₄ nanocluster at the molecular level.

ABSTRACT: Although chirality is an ever-present characteristic in biology and some artificial molecules, controlling the chirality and demystifying the chirality origin of complex assemblies remain challenging. Herein, we report two homochiral Ag₁₄ nanoclusters with inherent chirality originated from identical rotation of six square faces on a Ag₈ cube driven by intra-cluster π···π stacking interaction between pntp^- (Hpntp = p-nitrothiophenol) ligands. The spontaneous resolution of the racemic (SD/rac-Ag14a) to homochiral nanoclusters (SD/L-Ag14 and SD/R-Ag14) can be realized by re-crystallizing SD/rac-Ag14a in acetonitrile, which promotes the homochiral crystallization in solid state by forming C-H···O/N hydrogen bonds with nitro oxygen atoms in pntp^- or

SUBMITTER: Liang XQ 

PROVIDER: S-EPMC8371133 | biostudies-literature | 2021 Aug

REPOSITORIES: biostudies-literature