Investigation of iron-ammine and amido complexes within a C₃-symmetrical phosphinic amido tripodal ligand.

ABSTRACT: The primary and secondary coordination spheres can have large regulatory effects on the properties of metal complexes. To examine their influences on the properties of monomeric Fe complexes, the tripodal ligand containing phosphinic amido groups, N,N',N''-[nitrilotris(ethane-2,1-diyl)]tris(P,P-diphenylphosphinic amido) ([poat]^3-), was used to prepare [Fe^II/IIIpoat]^-/0 complexes. The Fe^II complex was four-coordinate with 4 N-atom donors comprising the primary coordination sphere. The Fe^III complex was six-coordinate with two additional ligands coming from coordination of O-atom donors on two of the phosphinic amido groups in [poat]^3-. In the crystalline phase, each complex was part of a cluster containing potassium ions in w

SUBMITTER: Sun C 

PROVIDER: S-EPMC8376781 | biostudies-literature | 2021 Aug

REPOSITORIES: biostudies-literature