EPTFE reinforced, sulfonated aromatic polymer membranes enable durable, high-temperature operable PEMFCs.

ABSTRACT: Sulfonated polyphenylene (SPP)-based ionomers have been developed for electrochemical applications in recent years due to their inherent thermal and chemical stability. However, the difficult synthesis, limited solubility, and rigid backbone obstructs their progress. Herein, a new monomer, 3,3″-dichloro-2',3',5',6'-tetrafluoro-1,1':4',1″-terphenyl (TP-f) with high polymerization reactivity was designed and polymerized with sulfonated phenylene monomer to prepare SPP-based ionomers (SPP-TP-f) with high ion exchange capacity up to 4.5 mequiv g^-1. The resulting flexible membranes were more proton conductive than Nafion (state-of-the-art proton exchange membrane) even at 120°C and 20% RH. Unlike typical SPP ionomers, SPP-TP-f 5.1 was soluble in ethanol and thus, could be reinforced 

SUBMITTER: Long Z 

PROVIDER: S-EPMC8379343 | biostudies-literature | 2021 Sep

REPOSITORIES: biostudies-literature