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A new organic–inorganic compound, ethylenediammonium hexachloridostannate(IV) p-anisaldehyde disolvate

ABSTRACT: This new organic–inorganic hybrid compound contains stacked sheets of ethylendiammonium cations and [SnCl6]2− anions with p-anisaldehyde molecules occupying occupying the space in between. The asymmetric unit of the title organic–inorganic hybrid complex [systematic name: ethane-1,2-diaminium hexachloridostannate(IV)–4-methoxybenzaldehyde (1/2)], (C2H10N2)[SnCl6]·2C8H8O2, contains one half of an ethylenediammonium cation, one half of an [SnCl6]2− anion and one p-anisaldehyde molecule. Both the organic cation and the quasi-regular octahedral inorganic anion are located about inversion centres. The organic cations and [SnCl6]2− anions lie in layers parallel to the ac plane with p-anisaldehyde molecules occupying the space between the layers. A network of classical N—H⋯Cl and N—H⋯O hydrogen bonds exists between the ethylenediammonium cations and the [SnCl6]2− anions and p-anisaldehyde molecules. These interactions, together with non-classical C—H⋯O interactions between the ethylenediammonium cations and the p-anisaldehyde molecules, serve to hold the structure together. The crystal studied was refined as a two-component twin.

SUBMITTER: Ndiolene A

PROVIDER: S-EPMC8382060 | biostudies-literature | 2021 Jun

REPOSITORIES: biostudies-literature

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