Toward Planar Iodine 2D Crystal Materials.

ABSTRACT: Usually, the octet rule determines whether an elemental 2D material can only be set by one of the elements in groups IIIA-VA, whose outmost electrons can form hybridized orbits from an s-wave and a p-wave. The hybridized orbits can accommodate all of the outermost electrons and form robust σ bonds. As for the elements in VIA-VIIA, the outermost electrons seem too abundant to be accommodated in hybridized orbits. Here, we show a spd² hybridization rule, accommodating all of the outermost electrons of halogen elements. Each atom can be connected to a contiguous atom by a robust σ bond and carries one dangling unpaired electron, implying that the formation of a π bond is possible. One iodine atomic layer can be robustly locked by the σ bond, forming an iodiene sheet by spd²

SUBMITTER: Zhang X 

PROVIDER: S-EPMC8387988 | biostudies-literature | 2021 Aug

REPOSITORIES: biostudies-literature