Counterion Migration Driven by Light-Induced Intramolecular Charge Transfer.

ABSTRACT: A series of D-π-A ⁺ pyridinium compounds, in which D = -NPh₂ and A⁺ = -PyMe⁺ are linked by various amounts of linear phenyl spacers, were strategically designed and synthesized. Their characterization revealed the presence of excited-state intramolecular charge transfer (ESICT) that triggers a corresponding response from the counterion. In medium and strong polar solvents, the fast solvent relaxation occurring after ESICT overwhelms the counterion effect, showing typical emission solvatochromism. In weakly polar solvents, ESICT induces counteranion migration for electrostatic stabilization, the time scale of which is dependent on the radius of the counteranion, the length of the π-linker, and the viscosity of the solvent. In low-viscosity

SUBMITTER: Lin TC 

PROVIDER: S-EPMC8395631 | biostudies-literature | 2021 Mar

REPOSITORIES: biostudies-literature