Bridging the Pressure Gap in CO Oxidation.

ABSTRACT: Performing fundamental operando catalysis studies under realistic conditions is a key to further develop and increase the efficiency of industrial catalysts. Operando X-ray photoelectron spectroscopy (XPS) experiments have been limited to pressures, and the relevance for industrial applications has been questioned. Herein, we report on the CO oxidation experiment on Pd(100) performed at a total pressure of 1 bar using XPS. We investigate the light-off regime and the surface chemical composition at the atomistic level in the highly active phase. Furthermore, the observed gas-phase photoemission peaks of CO₂, CO, and O₂ indicate that the kinetics of the reaction during the light-off regime can be followed operando, and by studying the reaction rate

SUBMITTER: Blomberg S 

PROVIDER: S-EPMC8397290 | biostudies-literature | 2021 Aug

REPOSITORIES: biostudies-literature