Design of Crystalline Reduction-Oxidation Cluster-Based Catalysts for Artificial Photosynthesis.

ABSTRACT: Metal cluster-based compounds have difficulty finishing the photocatalytic carbon dioxide reduction reaction (CO₂RR) and water oxidation reaction (WOR) simultaneously because of the big challenge in realizing the coexistence of independently and synergistically reductive and oxidative active sites in one compound. Herein, we elaborately designed and synthesized one kind of crystalline reduction-oxidation (RO) cluster-based catalysts connecting reductive {M ₃ L ₈ (H ₂ O) ₂ } (M = Zn, Co, and Ni for RO-1, 2, 3 respectively) cluster and oxidative {PMo₉V₇O₄₄} cluster through a single oxygen atom bridge to achieve artificial

SUBMITTER: Li XX 

PROVIDER: S-EPMC8397352 | biostudies-literature | 2021 Aug

REPOSITORIES: biostudies-literature