Studies of New Iridium Catalysts Supported on Modified Silicalite-1-Their Structure and Hydrogenating Properties.

ABSTRACT: This paper investigates the catalytic properties of the iridium catalysts supported on modified silicalite-1. Post-synthesis modification of silicalite-1, with solutions of ammonium compounds (NH₄F and NH₄OH), appeared to be an efficient method to generate the acidic sites in starting support. The modification of support led not only to changes in its acidity but also its porosity-formation of additional micro- and mesopores. The novel materials were used as supports for iridium. The iridium catalysts (1 wt.% Ir) were characterized by N₂ adsorption/desorption measurements, temperature-programmed reduction with hydrogen (TPR-H₂), H₂ chemisorption, transmission electron microscopy (TEM), temperature-programmed desorption of ammonia (TPD-NH₃), X-ray photoelectron spectroscopy (XPS) and tested in the hydrogenation of toluene reaction. The catalytic activity of iridium supported on silicalite-1 treated with NH₄OH (higher porosity of support, better dispersion of active phase) was much higher than that of Ir supported on unmodified and modified with NH₄F silicalite-1.

SUBMITTER: Zielinski M 

PROVIDER: S-EPMC8398754 | biostudies-literature | 2021 Aug

REPOSITORIES: biostudies-literature