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NOx Storage on BaTi0.8Cu0.2O3 Perovskite Catalysts: Addressing a Feasible Mechanism.

ABSTRACT: The NOx storage mechanism on BaTi0.8Cu0.2O3 catalyst were studied using different techniques. The results obtained by XRD, ATR, TGA and XPS under NOx storage-regeneration conditions revealed that BaO generated on the catalyst by decomposition of Ba2TiO4 plays a key role in the NOx storage process. In situ DRIFTS experiments under NO/O2 and NO/N2 show that nitrites and nitrates are formed on the perovskite during the NOx storage process. Thus, it seems that, as for model NSR catalysts, the NOx storage on BaTi0.8Cu0.2O3 catalyst takes place by both "nitrite" and "nitrate" routes, with the main pathway being highly dependent on the temperature and the time on stream: (i) at T < 350 °C, NO adsorption leads to nitrites formation on the catalyst and (ii) at T > 350 °C, the catalyst activity for NO oxidation promotes NO2 generation and the nitrate formation.

SUBMITTER: Albaladejo-Fuentes V

PROVIDER: S-EPMC8401998 | biostudies-literature | 2021 Aug

REPOSITORIES: biostudies-literature

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NOx Storage on BaTi0.8Cu0.2O3 Perovskite Catalysts: Addressing a Feasible Mechanism.

Albaladejo-Fuentes Vicente V Sánchez-Adsuar María-Salvadora MS Anderson James A JA Illán-Gómez María-José MJ

Nanomaterials (Basel, Switzerland) 20210821 8

The NOx storage mechanism on BaTi0.8Cu0.2O3 catalyst were studied using different techniques. The results obtained by XRD, ATR, TGA and XPS under NOx storage-regeneration conditions revealed that BaO generated on the catalyst by decomposition of Ba2TiO4 plays a key role in the NOx storage process. In situ DRIFTS experiments under NO/O2 and NO/N2 show that nitrites and nitrates are formed on the perovskite during the NOx ...[more]

PMID: 34443963

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