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Self-Assembled Hierarchical Cu _x O@C₁₈H₃₆O₂ Nanoflakes for Superior Fenton-like Catalysis over a Wide Range of pH.

ABSTRACT: A novel copper-based catalyst supported by a long-chain hydrocarbon stearic acid (Cu _x O@C₁₈H₃₆O₂) was synthesized by a hydrothermal method and double replacement reactions. The as-prepared catalyst is shown as self-assembled hierarchical nanoflakes with an average size of ∼22 nm and a specific surface area of 51.4 m² g^-1. The catalyst has a good performance on adsorption as well as Fenton-like catalytic degradation of Rhodamine B (RhB). The catalyst (10 mg/L) showed an excellent adsorption efficiency toward RhB (20 mg/L) for pH ranging from 5 to 13, with the highest adsorption rate (99%) exhibited at pH 13. The Fenton-like catalytic degradation reaction of RhB (20 mg/L) by Cu _x O@C₁₈H₃₆O₂ nanoflakes was effective over a wide range of pH of 3-11, and ^•OH radicals were generated via Cu₂O/H₂O₂ interactions in acidic conditions and CuO/H₂O₂ reactions in a neutral solution. The highest efficiency catalytic degradation of RhB (20 mg/L) was 99.2% under acidic conditions (pH = 3, H₂O₂ = 0.05 M), with an excellent reusability of 96% at the 6th cycle. The results demonstrated that the as-prepared Cu _x O@C₁₈H₃₆O₂ nanoflakes are an efficient candidate for wastewater treatment, with excellent adsorption capacity and superior Fenton-like catalytic efficiency and stability for RhB.

SUBMITTER: Rehman R

PROVIDER: S-EPMC8412932 | biostudies-literature | 2021 Aug

REPOSITORIES: biostudies-literature

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Self-Assembled Hierarchical Cu x O@C18H36O2 Nanoflakes for Superior Fenton-like Catalysis over a Wide Range of pH.

Rehman Ratul R Lahiri Sudip Kumar SK Islam Ashraful A Wei Peng P Xu Yue Y

ACS omega 20210818 34

A novel copper-based catalyst supported by a long-chain hydrocarbon stearic acid (Cu x O@C18H36O2) was synthesized by a hydrothermal method and double replacement reactions. The as-prepared catalyst is shown as self-assembled hierarchical nanoflakes with an average size of ∼22 nm and a specific surface area of 51.4 m2 g-1. The catalyst has a good performance on adsorption as well as Fenton-like catalytic degradation of Rhod ...[more]

PMID: 34497910

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Project description:New insensitive high explosives pose great challenges to conventional explosives manufacturing wastewater treatment processes and require advanced methods to effectively and efficiently mineralize these recalcitrant pollutants. Oxidation processes that utilize the fundamental techniques of Fenton chemistry optimized to overcome conventional limitations are vital to provide efficient degradation of these pollutants while maintaining cost-effectiveness and scalability. In this manner, utilizing heterogeneous catalysts and in-situ generated H2O2 to degrade IHEs is proposed. For heterogeneous catalyst optimization, varying the surface chemistry of activated carbon for use as a catalyst removes precipitation complications associated with iron species in Fenton chemistry while including removal by adsorption. Activated carbon impregnated with 5% MnO2 in the presence of H2O2 realized a high concentration of hydroxyl radical formation - 140 μM with 10 mM H2O2 - while maintaining low cost and relative ease of synthesis. This AC-Mn5 catalyst performed effectively over a wide pH range and in the presence of varying H2O2 concentrations with a sufficient effective lifetime. In-situ generation of H2O2 removes the logistical and economic constraints associated with external H2O2, with hydrophobic carbon electrodes utilizing generated gaseous O2 for 2-electron oxygen reduction reactions. In a novel flow-through reactor, gaseous O2 is generated on a titanium/mixed metal oxide anode with subsequent H2O2 electrogeneration on a hydrophobic microporous-layered carbon cloth cathode. This reactor is able to electrogenerate 2 mM H2O2 at an optimized current intensity of 150 mA and over a wide range of flow rates, influent pH values, and through multiple iterations. Coupling these two optimization methods realizes the production of highly oxidative hydroxyl radicals by Fenton-like catalysis of electrogenerated H2O2 on the surface of an MnO2-impregnated activated carbon catalyst. This method incorporates electrochemically induced oxidation of munitions in addition to removal by adsorption while maintaining cost-effectiveness and scalability. It is anticipated this platform holds great promise to eliminate analogous contaminants.

Dataset Information

Self-Assembled Hierarchical Cu _x O@C₁₈H₃₆O₂ Nanoflakes for Superior Fenton-like Catalysis over a Wide Range of pH.

Publications

Self-Assembled Hierarchical Cu <i><sub>x</sub></i> O@C<sub>18</sub>H<sub>36</sub>O<sub>2</sub> Nanoflakes for Superior Fenton-like Catalysis over a Wide Range of pH.

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