Single-atom catalyst for high-performance methanol oxidation.

ABSTRACT: Single-atom catalysts have been widely investigated for several electrocatalytic reactions except electrochemical alcohol oxidation. Herein, we synthesize atomically dispersed platinum on ruthenium oxide (Pt₁/RuO₂) using a simple impregnation-adsorption method. We find that Pt₁/RuO₂ has good electrocatalytic activity towards methanol oxidation in an alkaline media with a mass activity that is 15.3-times higher than that of commercial Pt/C (6766 vs. 441 mA mg^‒1_Pt). In contrast, single atom Pt on carbon black is inert. Further, the mass activity of Pt₁/RuO₂ is superior to that of most Pt-based catalysts previously developed. Moreover, Pt₁/RuO₂ has a high tolerance towards CO poisonin

SUBMITTER: Zhang Z 

PROVIDER: S-EPMC8413426 | biostudies-literature | 2021 Sep

REPOSITORIES: biostudies-literature