Fabrication of Highly Interconnected Poly(ε-caprolactone)/cellulose Nanofiber Composite Foams by Microcellular Foaming and Leaching Processes.

ABSTRACT: In this study, microcellular polycaprolactone (PCL)/sodium bicarbonate (NaHCO₃)/cellulose nanofiber (CNF) composite foams with highly interconnected porous structures were successfully fabricated by microcellular foaming and particle leaching processes. Supercritical CO₂ (scCO₂) served as a physical foaming agent, NaHCO₃ was chosen as a chemical foaming agent and porogen, and CNF acted as a heterogeneous nucleating agent. The effect of scCO₂, NaHCO₃, and CNF on pore structures and the cofoaming mechanism were investigated. The results indicated that the addition of NaHCO₃ and CNF increased the melt strength of the PCL matrix significantly. During the foaming process, the presence of CNF can form a rigid network du

SUBMITTER: Li J 

PROVIDER: S-EPMC8427651 | biostudies-literature | 2021 Sep

REPOSITORIES: biostudies-literature