Reductive Electropolymerization and Electrochromism of Iron(II) Complex with Styrene-Based Ligand.

ABSTRACT: The benzimidazole-based ligand containing polymerizable styrene group has been prepared via condensation of picolinaldehyde derivative containing styrene moiety and benzimidazole-based hydrazine. The ligand reacted with iron(II) tetrafluoroborate and iron(II) trifluoromethanesulfonate giving red-brown complexes of Fe(II) ions of formula [FeL2]X2, where X = CF3SO3- (1) or BF4- (2). Reductive electropolymerization was used to obtain a thin layer of the polymeric complex, poly-1. Further investigation of electrochemical properties of the compound by cyclic voltammetry showed two quasi-reversible redox processes assigned to electrooxidation and electroreduction of the polymer. Spectroelectrochemical measurements confirmed that the polymer undergoes the color changes during oxidation and reduct

SUBMITTER: Napierala S 

PROVIDER: S-EPMC8432686 | biostudies-literature | 2021 Aug

REPOSITORIES: biostudies-literature