Characterizing azobenzene disperse dyes in commercial mixtures and children's polyester clothing.

ABSTRACT: Azobenzene disperse dyes are the fastest-growing class of dyestuffs, yet little is known about dye occurrences, sources, and transformations; azo dyes are also underrepresented in chemical standard catalogs, molecular databases, and mass spectral libraries. Many azo dyes are known to have sensitization, mutagenic, and carcinogenic properties. To fill these knowledge gaps, azo dyes were purified from dyestuffs by Soxhlet extraction and flash chromatography and characterized using ultra-high-performance liquid chromatography (UHPLC) coupled to a high resolution Orbitrap Fusion Lumos mass spectrometer operated in positive electrospray ionization mode, as well as by ¹H and ¹³C NMR. Data were analyzed to identify likely chemical formulas and structures using a weight-of-ev

SUBMITTER: Overdahl KE 

PROVIDER: S-EPMC8434964 | biostudies-literature | 2021 Oct

REPOSITORIES: biostudies-literature