Enhanced medium-range order in vapor-deposited germania glasses at elevated temperatures.

ABSTRACT: Glasses are nonequilibrium solids with properties highly dependent on their method of preparation. In vapor-deposited molecular glasses, structural organization could be readily tuned with deposition rate and substrate temperature. Here, we show that the atomic arrangement of strong network-forming GeO₂ glass is modified at medium range (<2 nm) through vapor deposition at elevated temperatures. Raman spectral signatures distinctively show that the population of six-membered GeO₄ rings increases at elevated substrate temperatures. Deposition near the glass transition temperature is more efficient than postgrowth annealing in modifying atomic structure at medium range. The enhanced medium-range organization correlates with reduction of the room temperature internal fric

SUBMITTER: Yang L 

PROVIDER: S-EPMC8442899 | biostudies-literature | 2021 Sep

REPOSITORIES: biostudies-literature