Two-dimensional molybdenum carbide 2D-Mo₂C as a superior catalyst for CO₂ hydrogenation.

ABSTRACT: Early transitional metal carbides are promising catalysts for hydrogenation of CO₂. Here, a two-dimensional (2D) multilayered 2D-Mo₂C material is prepared from Mo₂CT_x of the MXene family. Surface termination groups T_x (O, OH, and F) are reductively de-functionalized in Mo₂CT_x (500 °C, pure H₂) avoiding the formation of a 3D carbide structure. CO₂ hydrogenation studies show that the activity and product selectivity (CO, CH₄, C₂-C₅ alkanes, methanol, and dimethyl ether) of Mo₂CT_x and 2D-Mo₂C are controlled by the surface coverage of T_x groups that are tunable by the H₂ pretreatment conditions. 2D-Mo₂

SUBMITTER: Zhou H 

PROVIDER: S-EPMC8448824 | biostudies-literature | 2021 Sep

REPOSITORIES: biostudies-literature