Dataset Information

Synthesis and Characterization of Bis[(R or S)-N-1-(X-C₆H₄)ethyl-2-oxo-1-naphthaldiminato-κ²N,O]-Λ/Δ-cobalt(II) (X = H, p-CH₃O, p-Br) with Symmetry- and Distance-Dependent Vibrational Circular Dichroism Enhancement and Sign Inversion.

ABSTRACT: The enantiopure Schiff bases (R or S)-N-1-(X-C₆H₄)ethyl-2-hydroxy-1-naphthaldimine {X = H [(R or S)-HL1], p-CH₃O [(R or S)-HL2], and p-Br [(R- or S)-HL3]} react with cobalt(II) acetate to give bis[(R or S)-N-1-(X-C₆H₄)ethyl-2-oxo-1-naphthaldiminato-κ²N,O]-Λ/Δ-cobalt(II) {X = H [Λ/Δ-Co-(R or S)-L1], p-CH₃O [Λ/Δ-Co-(R or S)-L2], and p-Br [Λ/Δ-Co-(R or S)-L3]} (1-3), respectively. Induced Λ and Δ chirality originates at the metal center of the C₂-symmetric molecule in pseudotetrahedral geometry. Differential scanning cal

SUBMITTER: Gorecki M

PROVIDER: S-EPMC8456410 | biostudies-literature | 2021 Sep

REPOSITORIES: biostudies-literature

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Dataset Information

Synthesis and Characterization of Bis[(R or S)-N-1-(X-C₆H₄)ethyl-2-oxo-1-naphthaldiminato-κ²N,O]-Λ/Δ-cobalt(II) (X = H, p-CH₃O, p-Br) with Symmetry- and Distance-Dependent Vibrational Circular Dichroism Enhancement and Sign Inversion.

OmicsDI is part of the ELIXIR infrastructure

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Dataset Information

Synthesis and Characterization of Bis[(R or S)-N-1-(X-C6H4)ethyl-2-oxo-1-naphthaldiminato-κ2N,O]-Λ/Δ-cobalt(II) (X = H, p-CH3O, p-Br) with Symmetry- and Distance-Dependent Vibrational Circular Dichroism Enhancement and Sign Inversion.

OmicsDI is part of the ELIXIR infrastructure

Tweets

Synthesis and Characterization of Bis[(R or S)-N-1-(X-C₆H₄)ethyl-2-oxo-1-naphthaldiminato-κ²N,O]-Λ/Δ-cobalt(II) (X = H, p-CH₃O, p-Br) with Symmetry- and Distance-Dependent Vibrational Circular Dichroism Enhancement and Sign Inversion.