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Triazine-Based Conjugated Microporous Polymers for Efficient Hydrogen Production.

ABSTRACT: Developing visible-light-active porous organic polymers with high photocatalytic efficiency is highly desirable. Here, two triazine-based conjugated microporous polymers were synthesized. The structures were controllably adjusted to explore the structure-photocatalytic activity relationship. T-CMP-1 containing more triazine units exhibited a hydrogen evolution rate of 3214.3 μmol h^-1 g^-1, much higher than that of T-CMP-2 (242.1 μmol h^-1 g^-1). The increasing contents of triazine units bring better hydrogen evolution efficiency.

SUBMITTER: Hao W

PROVIDER: S-EPMC8459349 | biostudies-literature | 2021 Sep

REPOSITORIES: biostudies-literature

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Triazine-Based Conjugated Microporous Polymers for Efficient Hydrogen Production.

Hao Wenbo W Chen Renzeng R Zhang Yue Y Wang Yuancheng Y Zhao Yingjie Y

ACS omega 20210908 37

Developing visible-light-active porous organic polymers with high photocatalytic efficiency is highly desirable. Here, two triazine-based conjugated microporous polymers were synthesized. The structures were controllably adjusted to explore the structure-photocatalytic activity relationship. T-CMP-1 containing more triazine units exhibited a hydrogen evolution rate of 3214.3 μmol h-1 g-1, much higher than that of T-CMP-2 (242.1 μmol h-1 g-1</su ...[more]

PMID: 34568658

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