Biomimetic Nanocomposite Membranes with Ultrahigh Ion Selectivity for Osmotic Power Conversion.

ABSTRACT: Ion transport in nanoconfinement exhibits significant features such as ionic rectification, ionic selectivity, and ionic gating properties, leading to the potential applications in desalination, water treatment, and energy conversion. Two-dimensional nanofluidics provide platforms to utilize this phenomenon for capturing osmotic energy. However, it is challenging to further improve the power output with inadequate charge density. Here we demonstrate a feasible strategy by employing Kevlar nanofiber as space charge donor and cross-linker to fabricate graphene oxide composite membranes. The coupling of space charge and surface charge, enabled by the stabilization of interlayer spacing, plays a key role in realizing high ion selectivity and the derived high-performance osmotic power conversion up to 5.06 W/m². Furthermore, the output voltage of an ensemble of the membranes in series could reach 1.61 V, which can power electronic devices. The system contributes a further step toward the application of energy conversion.

SUBMITTER: Chen J 

PROVIDER: S-EPMC8461767 | biostudies-literature | 2021 Sep

REPOSITORIES: biostudies-literature