N-Doped Biochar as a New Metal-Free Activator of Peroxymonosulfate for Singlet Oxygen-Dominated Catalytic Degradation of Acid Orange 7.

ABSTRACT: In this paper, using rice straw as a raw material and urea as a nitrogen precursor, a composite catalyst (a nitrogen-doped rice straw biochar at the pyrolysis temperature of 800 °C, recorded as NRSBC800) was synthesized by one-step pyrolysis. NRSBC800 was then characterized using XPS, BET, TEM and other technologies, and its catalytic performance as an activator for permonosulfate (PMS) to degrade acid orange 7 (AO7) was studied. The results show that the introduction of N-doping significantly improved the catalytic performance of NRSBC800. The NRSBC800/PMS oxidation system could fully degrade AO7 within 30 min, with the reaction rate constant (2.1 × 10 -1 min-1) being 38 times that of RSBC800 (5.5 × 10-3 min-1). Moreover, NRSBC800 not only had better catalytic performance than traditional

SUBMITTER: Han R 

PROVIDER: S-EPMC8471211 | biostudies-literature | 2021 Sep

REPOSITORIES: biostudies-literature