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Tetracarbonyl group 6B metal complexes of a N-(4-acetylphenyl)-N-(diphenylphosphino)amine ligand. Molecular structure of cis-[Cr(CO)₄{4-CH₃CO-C₆H₄-1-N(PPh₂)₂}].

ABSTRACT: Chemical reactions of N-(4-acetylphenyl)-N-(diphenylphosphino)amine ligand (1) with three group 6B metal hexacarbonyls produced cis-M(CO)₄[1-_k ² P,P][ M = Cr(2), Mo(3), W(4)], respectively. The novel complexes 2-4 were isolated and their structures were elucidated by multinuclear NMR spectroscopy (¹H, ¹³C, ³¹P NMR) and elemental analysis. Crystal-structure determination using single-crystal X-ray diffraction was carried out on complex 2.

SUBMITTER: Al-Masri HT

PROVIDER: S-EPMC8477991 | biostudies-literature | 2021 Sep

REPOSITORIES: biostudies-literature

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Tetracarbonyl group 6B metal complexes of a N-(4-acetylphenyl)-N-(diphenylphosphino)amine ligand. Molecular structure of cis-[Cr(CO)₄{4-CH₃CO-C₆H₄-1-N(PPh₂)₂}].

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Tetracarbonyl group 6B metal complexes of a N-(4-acetylphenyl)-N-(diphenylphosphino)amine ligand. Molecular structure of cis-[Cr(CO)4{4-CH3CO-C6H4-1-N(PPh2)2}].

OmicsDI is part of the ELIXIR infrastructure

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Tetracarbonyl group 6B metal complexes of a N-(4-acetylphenyl)-N-(diphenylphosphino)amine ligand. Molecular structure of cis-[Cr(CO)₄{4-CH₃CO-C₆H₄-1-N(PPh₂)₂}].