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Step by Step Construction of Multifunctional Hollow Double Shell MNPs@MOF as a Powerful Tandem/Cascade Catalyst.

ABSTRACT: The development of efficient heterogeneous catalysts for one-pot tandem/cascade synthesis of imines remains meaningful and challenging. Herein, we constructed an Au/MOF catalyst featured hollow and double MOF shell nanostructure. Owing to its structural merits and acid-basic nature, the as-synthesized Void|(Au)ZIF-8|ZIF-8 catalyst exhibited an enhanced synergistically catalytic performance for tandem catalytic synthesis of imines from benzyl alcohol and aniline under air atmosphere and solvent-free condition. Its 170.16 h^-1 of turnover frequency (TOF) was 2.5 times higher than that of the reported catalyst with the highest TOF value.

SUBMITTER: Shi S

PROVIDER: S-EPMC8479107 | biostudies-literature | 2021

REPOSITORIES: biostudies-literature

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Step by Step Construction of Multifunctional Hollow Double Shell MNPs@MOF as a Powerful Tandem/Cascade Catalyst.

Shi Shunli S Yu Ying Y Zhang Bingzhen B Zhong Yicheng Y Wang Lei L Wang Shuhua S Ding Shunmin S Chen Chao C

Frontiers in chemistry 20210915

The development of efficient heterogeneous catalysts for one-pot tandem/cascade synthesis of imines remains meaningful and challenging. Herein, we constructed an Au/MOF catalyst featured hollow and double MOF shell nanostructure. Owing to its structural merits and acid-basic nature, the as-synthesized Void|(Au)ZIF-8|ZIF-8 catalyst exhibited an enhanced synergistically catalytic performance for tandem catalytic synthesis of imines from benzyl alcohol and aniline under air atmosphere and solvent-f ...[more]

PMID: 34604171

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