Low-spin ferric iron in primordial bridgmanite crystallized from a deep magma ocean.

ABSTRACT: The crystallization of the magma ocean resulted in the present layered structure of the Earth's mantle. An open question is the electronic spin state of iron in bridgmanite (the most abundant mineral on Earth) crystallized from a deep magma ocean, which has been neglected in the crystallization history of the entire magma ocean. Here, we performed energy-domain synchrotron Mössbauer spectroscopy measurements on two bridgmanite samples synthesized at different pressures using the same starting material (Mg_0.78Fe_0.13Al_0.11Si_0.94O₃). The obtained Mössbauer spectra showed no evidence of low-spin ferric iron (Fe³⁺) from the bridgmanite sample synthesized at relatively low pressure of 25 gigapascals, while that directly synthesize

SUBMITTER: Okuda Y 

PROVIDER: S-EPMC8484549 | biostudies-literature | 2021 Sep

REPOSITORIES: biostudies-literature