Efficient CO₂ electroreduction on facet-selective copper films with high conversion rate.

ABSTRACT: Tuning the facet exposure of Cu could promote the multi-carbon (C2+) products formation in electrocatalytic CO₂ reduction. Here we report the design and realization of a dynamic deposition-etch-bombardment method for Cu(100) facets control without using capping agents and polymer binders. The synthesized Cu(100)-rich films lead to a high Faradaic efficiency of 86.5% and a full-cell electricity conversion efficiency of 36.5% towards C2+ products in a flow cell. By further scaling up the electrode into a 25 cm² membrane electrode assembly system, the overall current can ramp up to 12 A while achieving a single-pass yield of 13.2% for C2+ products. An insight into the influence of Cu facets exposure on intermediates is provided by in situ spectroscopic methods supported

SUBMITTER: Zhang G 

PROVIDER: S-EPMC8484611 | biostudies-literature | 2021 Sep

REPOSITORIES: biostudies-literature