Proton Relay in Iron Porphyrins for Hydrogen Evolution Reaction.

ABSTRACT: The efficiency of the hydrogen evolution reaction (HER) can be facilitated by the presence of proton-transfer groups in the vicinity of the catalyst. A systematic investigation of the nature of the proton-transfer groups present and their interplay with bulk proton sources is warranted. The HERs electrocatalyzed by a series of iron porphyrins that vary in the nature and number of pendant amine groups are investigated using proton sources whose pK_a values vary from ∼9 to 15 in acetonitrile. Electrochemical data indicate that a simple iron porphyrin (FeTPP) can catalyze the HER at this Fe^I state where the rate-determining step is the intermolecular protonation of a Fe^III-H^- species produced upon protonation of the iron(I) porphyrin and does

SUBMITTER: Bhunia S 

PROVIDER: S-EPMC8485179 | biostudies-literature | 2021 Sep

REPOSITORIES: biostudies-literature